Issue 76, 2017

A novel polyoxometalate-based hybrid containing a 2D [CoMo8O26] structure as the anode for lithium-ion batteries

Abstract

The proof-of-principle of an unusual fused γ-[Mo8O26]4− chain as an inorganic ligand is presented for the first time. By sharing two Mo–O edges, the γ-[Mo8O26]4− subunits are propagated into a one-dimensional (1D) zig-zag chain, which acts as a purely inorganic ligand binding octahedral Co(II) centers into a two-dimensional (2D) [CoMo8O26] sheet. This material exhibits high initial reversible specific capacity and stable reversible capacity when applied as an anode for lithium-ion batteries (LIBs).

Graphical abstract: A novel polyoxometalate-based hybrid containing a 2D [CoMo8O26]∞ structure as the anode for lithium-ion batteries

Supplementary files

Article information

Article type
Communication
Submitted
24 Jul 2017
Accepted
01 Sep 2017
First published
01 Sep 2017

Chem. Commun., 2017,53, 10560-10563

A novel polyoxometalate-based hybrid containing a 2D [CoMo8O26] structure as the anode for lithium-ion batteries

X. Chen, Z. Wang, R. Zhang, L. Xu and D. Sun, Chem. Commun., 2017, 53, 10560 DOI: 10.1039/C7CC05741E

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