Issue 83, 2017
From the journal:

Chemical Communications

Synthesis of trinorbornane†

Lorenzo Delarue Bizzini,a   Thomas Müntener,a   Daniel Häussinger, ORCID logo a   Markus Neuburger ORCID logo a  and  Marcel Mayor ORCID logo *abc  

* Corresponding authors

a Department of Chemistry, University of Basel, St. Johanns-Ring 19, 4056 Basel, Switzerland
E-mail: marcel.mayor@unibas.ch

b Institute for Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), P. O. Box 3640, 76021 Karlsruhe, Germany

c Lehn Institute of Functional Materials (LIFM), Sun Yat Sen University (SYSU), XinGangXi Rd. 135, 510275 Guangzhou, P. R. China

Abstract

Herein we report the synthesis and characterisation of the until recently unreported chiral C11 skeleton of tetracyclo[5.2.2.01,6.04,9]undecane (“trinorbornane”) which could be obtained in 7% overall yield in 9 steps. This new rigid structural type was found to be present in the computer generated Chemical Universe Data-base (GDB) and has until now no real-world counterpart.

Graphical abstract: Synthesis of trinorbornane

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7CC06273G
Article type
Communication
Submitted
10 Aug 2017
Accepted
26 Sep 2017
First published
26 Sep 2017

Chem. Commun., 2017,53, 11399-11402

Permissions

Request permissions

Synthesis of trinorbornane

L. Delarue Bizzini, T. Müntener, D. Häussinger, M. Neuburger and M. Mayor, Chem. Commun., 2017, 53, 11399 DOI: 10.1039/C7CC06273G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements