Issue 10, 2018
From the journal:

Chemical Communications

Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications†‡

Victoria A. Pollard,a   Samantha A. Orr,a   Ross McLellan,a   Alan R. Kennedy, ORCID logo a   Eva Hevia ORCID logo a  and  Robert E. Mulvey ORCID logo *a  

* Corresponding authors

a WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK
E-mail: r.e.mulvey@strath.ac.uk

Abstract

Cooperativity between the Li and Al centres is implicated in catalytic hydroboration reactions of aldehydes and ketones with pinacolborane via heteroleptic lithium diamidodihydridoaluminates. In addition to implementing hydroalumination, these versatile heteroleptic ates can also perform as amido bases as illustrated with an acidic triazole.

Graphical abstract: Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications

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Article information

DOI
https://doi.org/10.1039/C7CC08214B
Article type
Communication
Submitted
24 Oct 2017
Accepted
29 Nov 2017
First published
16 Jan 2018
This article is Open Access
Creative Commons BY license

Chem. Commun., 2018,54, 1233-1236

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Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications

V. A. Pollard, S. A. Orr, R. McLellan, A. R. Kennedy, E. Hevia and R. E. Mulvey, Chem. Commun., 2018, 54, 1233 DOI: 10.1039/C7CC08214B

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