Issue 18, 2018

Ambient chemical fixation of CO2 using a highly efficient heterometallic helicate catalyst system

Abstract

Two novel heptanuclear 3d–4f helicates have been synthesized and characterized. The helicates act as catalysts and show high catalytic activity for the coupling of CO2 and epoxides to obtain cyclic carbonates with a wide substrate scope at ambient temperature and pressure.

Graphical abstract: Ambient chemical fixation of CO2 using a highly efficient heterometallic helicate catalyst system

Supplementary files

Article information

Article type
Communication
Submitted
27 Nov 2017
Accepted
21 Dec 2017
First published
21 Dec 2017

Chem. Commun., 2018,54, 2212-2215

Ambient chemical fixation of CO2 using a highly efficient heterometallic helicate catalyst system

L. Wang, C. Xu, Q. Han, X. Tang, P. Zhou, R. Zhang, G. Gao, B. Xu, W. Qin and W. Liu, Chem. Commun., 2018, 54, 2212 DOI: 10.1039/C7CC09092G

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