Issue 26, 2018

Sulfonamides as new hydrogen atom transfer (HAT) catalysts for photoredox allylic and benzylic C–H arylations

Abstract

A catalytic amount of a sterically and electronically tuned diarylsulfonamide promoted allylic and benzylic C–H arylations in cooperation with a visible light photoredox catalyst. This is the first example of the catalytic use of a sulfonamidyl radical to promote the hydrogen atom transfer process.

Graphical abstract: Sulfonamides as new hydrogen atom transfer (HAT) catalysts for photoredox allylic and benzylic C–H arylations

Supplementary files

Article information

Article type
Communication
Submitted
09 Dec 2017
Accepted
29 Jan 2018
First published
29 Jan 2018

Chem. Commun., 2018,54, 3215-3218

Sulfonamides as new hydrogen atom transfer (HAT) catalysts for photoredox allylic and benzylic C–H arylations

H. Tanaka, K. Sakai, A. Kawamura, K. Oisaki and M. Kanai, Chem. Commun., 2018, 54, 3215 DOI: 10.1039/C7CC09457D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements