Built-in TTF–TCNQ charge-transfer salts in π-stacked pillared layer frameworks

Yoshihiro Sekine; Masanori Tonouchi; Taiga Yokoyama; Wataru Kosaka; Hitoshi Miyasaka

doi:10.1039/C7CE00492C

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Built-in TTF–TCNQ charge-transfer salts in π-stacked pillared layer frameworks†

Yoshihiro Sekine,^ab Masanori Tonouchi,^c Taiga Yokoyama,^b Wataru Kosaka^ab and Hitoshi Miyasaka

*^ab

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* Corresponding authors

^a Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan
E-mail: miyasaka@imr.tohoku.ac.jp

^b Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, Japan

^c Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan

Abstract

A TTF–TCNQ charge-transfer salt was incorporated in a layer structure with paddlewheel-type carboxylate-bridged dirhodium(II, II) complexes ([Rh₂]) to construct π-stacked pillared layer frameworks of formula (TTF)_n[{Rh}₂(TCNQ)] (n = 1 or 2).

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Article information

DOI: https://doi.org/10.1039/C7CE00492C
Article type: Communication
Submitted: 13 Mar 2017
Accepted: 05 Apr 2017
First published: 05 Apr 2017

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CrystEngComm, 2017,19, 2300-2304

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Built-in TTF–TCNQ charge-transfer salts in π-stacked pillared layer frameworks

Y. Sekine, M. Tonouchi, T. Yokoyama, W. Kosaka and H. Miyasaka, CrystEngComm, 2017, 19, 2300 DOI: 10.1039/C7CE00492C

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CrystEngComm

Built-in TTF–TCNQ charge-transfer salts in π-stacked pillared layer frameworks†

Abstract

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Built-in TTF–TCNQ charge-transfer salts in π-stacked pillared layer frameworks

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