Issue 22, 2017
From the journal:

Dalton Transactions

Redox effects of low-spin Ru(ii/iii) on slow magnetic relaxation of Ru–Mn(iii) 1D cyanide-bridged complexes†

Xiaoquan Zhu,ab   Shaodong Su,ab   Wenhai Cao,ab   Yuehong Wen,a   Shengmin Hu,a   Xintao Wu ORCID logo a  and  Tianlu Sheng ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China
E-mail: tsheng@fjirsm.ac.cn

b School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing, China

Abstract

A new one-dimensional cyanide-bridged complex [MnIII(salphen)RuII(DMAP)4(CN)2](PF6) (1) and its oxidized derivative [MnIII(salphen)RuIII(DMAP)4(CN)2](PF6)2 (2) have been synthesized and fully characterized. Magnetic measurements showed that 1 shows simple paramagnetism but 2 shows intrachain ferromagnetic interaction with slow magnetic relaxation.

Graphical abstract: Redox effects of low-spin Ru(ii/iii) on slow magnetic relaxation of Ru–Mn(iii) 1D cyanide-bridged complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7DT01218G
Article type
Paper
Submitted
05 Apr 2017
Accepted
06 May 2017
First published
08 May 2017

Dalton Trans., 2017,46, 7267-7272

Permissions

Request permissions

Redox effects of low-spin Ru(II/III) on slow magnetic relaxation of Ru–Mn(III) 1D cyanide-bridged complexes

X. Zhu, S. Su, W. Cao, Y. Wen, S. Hu, X. Wu and T. Sheng, Dalton Trans., 2017, 46, 7267 DOI: 10.1039/C7DT01218G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements