Issue 25, 2017

Generation and characterisation of a stable nickel(ii)-aminoxyl radical complex

Abstract

A stable nickel(II)-aminoxyl radical complex was generated by the reaction of a nickel(II) complex supported by a tren ligand (tris(2-aminoethyl)amine) having bulky m-terphenyl substituents (TIPT: 3,5-bis(2,6-diisopropylphenyl)phenyl) and m-CPBA (m-chloroperoxybenzoic acid). The formation mechanism of the nickel(II)-aminoxyl radical complex was examined.

Graphical abstract: Generation and characterisation of a stable nickel(ii)-aminoxyl radical complex

Supplementary files

Article information

Article type
Communication
Submitted
17 May 2017
Accepted
01 Jun 2017
First published
01 Jun 2017

Dalton Trans., 2017,46, 8013-8016

Generation and characterisation of a stable nickel(II)-aminoxyl radical complex

A. Parrot, Y. Morimoto, S. Paria, H. Sugimoto, N. Fujieda and S. Itoh, Dalton Trans., 2017, 46, 8013 DOI: 10.1039/C7DT01789H

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