Issue 34, 2017

A versatile route to homo- and hetero-bimetallic 5f–5f and 3d–5f complexes supported by a redox active ligand framework

Abstract

The salt-elimination reaction of the complex [Na2U(bis-salophen)] with metal halides provides an entry to the synthesis of well-defined homobimetallic uranium–uranium and rare heterobimetallic uranium–cobalt and uranium–nickel complexes supported by a redox-active dinucleating ligand.

Graphical abstract: A versatile route to homo- and hetero-bimetallic 5f–5f and 3d–5f complexes supported by a redox active ligand framework

Supplementary files

Article information

Article type
Communication
Submitted
01 Jun 2017
Accepted
08 Jun 2017
First published
26 Jun 2017

Dalton Trans., 2017,46, 11145-11148

A versatile route to homo- and hetero-bimetallic 5f–5f and 3d–5f complexes supported by a redox active ligand framework

C. Camp, D. Toniolo, J. Andrez, J. Pécaut and M. Mazzanti, Dalton Trans., 2017, 46, 11145 DOI: 10.1039/C7DT01993A

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