Issue 33, 2017

A mononuclear Co(ii) complex formed from pyridinedimethanol with manifold slow relaxation channels

Abstract

A mononuclear hexacoordinate complex [Co(pydm)2](dnbz)2 formed from 2,6-pyridinedimethanol in the coordination sphere of Co(II) and dinitrobenzoato anions exhibits magnetic anisotropy of an easy axis type and a field induced slow magnetic relaxation with manifold relaxation channels. The low-frequency relaxation time is as slow as τLF = 0.13 s at BDC = 0.4 T and T = 1.9 K.

Graphical abstract: A mononuclear Co(ii) complex formed from pyridinedimethanol with manifold slow relaxation channels

Supplementary files

Article information

Article type
Paper
Submitted
12 Jun 2017
Accepted
20 Jul 2017
First published
20 Jul 2017

Dalton Trans., 2017,46, 10950-10956

A mononuclear Co(II) complex formed from pyridinedimethanol with manifold slow relaxation channels

D. Valigura, C. Rajnák, J. Moncol, J. Titiš and R. Boča, Dalton Trans., 2017, 46, 10950 DOI: 10.1039/C7DT02131C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements