Issue 23, 2017

A disc-like Co7 cluster with a solvent dependent catecholase activity

Abstract

A new mixed valence antiferromagnetic Co7 disc characterized by spectral, crystallographic and magnetic studies exhibited a solvent dependent catecholase activity with Kcat(MeOH) = 2026 h−1. This report demonstrates the first example of a discrete heptanuclear disc showing solvent dependent catecholase activity.

Graphical abstract: A disc-like Co7 cluster with a solvent dependent catecholase activity

Supplementary files

Article information

Article type
Letter
Submitted
22 Aug 2017
Accepted
20 Oct 2017
First published
20 Oct 2017

New J. Chem., 2017,41, 14057-14061

A disc-like Co7 cluster with a solvent dependent catecholase activity

M. N. Ahamad, F. Sama, M. N. Akhtar, Y. Chen, M. Tong, M. Ahmad, M. Shahid, S. Hussain and K. Khan, New J. Chem., 2017, 41, 14057 DOI: 10.1039/C7NJ03149A

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