Issue 9, 2017

β-Fluorinated porpholactones and metal complexes: synthesis, characterization and some spectroscopic studies

Abstract

We describe the synthesis of β-fluorinated porpholactones by oxidation of the fluorinated C[double bond, length as m-dash]C bond of the pyrrolic subunit in porphyrin using the “RuCl3 + Oxone®” protocol. The electron-withdrawing effects of β-fluorine on the absorption, fluorescence, phosphorescence and redox properties of the β-fluoroporpholactones were studied. A potential application of the β-fluoroporpholactones was demonstrated in sensitizing near-IR (NIR) emissive ytterbium, giving a high quantum yield (58%) and long luminescence time (525 μs) in CD2Cl2.

Graphical abstract: β-Fluorinated porpholactones and metal complexes: synthesis, characterization and some spectroscopic studies

Supplementary files

Article information

Article type
Research Article
Submitted
03 Jul 2017
Accepted
21 Jul 2017
First published
24 Jul 2017

Inorg. Chem. Front., 2017,4, 1539-1545

β-Fluorinated porpholactones and metal complexes: synthesis, characterization and some spectroscopic studies

J. Hu, Z. Wu, K. Chai, Z. Yang, Y. Meng, Y. Ning, J. Zhang and J. Zhang, Inorg. Chem. Front., 2017, 4, 1539 DOI: 10.1039/C7QI00375G

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