Cu-Induced [H6W12O42]6− polyoxometalate-based bimetallic cluster formation for renewable biomass inulin hydrolysis toward fructose production

Yongdong Chen; Chaolei Zhang; Jiangwei Zhang; Zhongbin Ye; Kai Zheng; Qihua Fang; Gao Li

doi:10.1039/C7QI00516D

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Cu-Induced [H₆W₁₂O₄₂]⁶⁻ polyoxometalate-based bimetallic cluster formation for renewable biomass inulin hydrolysis toward fructose production†

Yongdong Chen,^ab Chaolei Zhang,^ab Jiangwei Zhang,

*^b Zhongbin Ye,^a Kai Zheng,^b Qihua Fang^b and Gao Li

*^b

Author affiliations

* Corresponding authors

^a College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China

^b Gold Catalysis Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
E-mail: gaoli@dicp.ac.cn, jwzhang@dicp.ac.cn

Abstract

Herein, a novel 3D open bimetallic Cu₃[H₆W₁₂O₄₂] cluster was designed as an effective solid acid catalyst for the hydrolysis of renewable biomass inulin by heterogeneous catalytic reaction towards fructose production with a high inulin conversion (∼100%) and fructose selectivity (∼90%) at low temperatures under aqueous condition with economic feasibility.

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Article information

DOI: https://doi.org/10.1039/C7QI00516D
Article type: Research Article
Submitted: 25 Aug 2017
Accepted: 11 Oct 2017
First published: 12 Oct 2017

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Inorg. Chem. Front., 2017,4, 1917-1922

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Cu-Induced [H₆W₁₂O₄₂]⁶⁻ polyoxometalate-based bimetallic cluster formation for renewable biomass inulin hydrolysis toward fructose production

Y. Chen, C. Zhang, J. Zhang, Z. Ye, K. Zheng, Q. Fang and G. Li, Inorg. Chem. Front., 2017, 4, 1917 DOI: 10.1039/C7QI00516D

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