Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers

Akio Mishima; Tomomi Koshiyama; Jose A. Real; Masaaki Ohba

doi:10.1039/C7TC00751E

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Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers†

Akio Mishima,^a Tomomi Koshiyama,^a Jose A. Real^b and Masaaki Ohba

*^a

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* Corresponding authors

^a Department of Chemistry, Graduate School of Science, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan
E-mail: ohba@chem.kyushu-univ.jp

^b Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, 46980 Paterna, Spain

Abstract

Mesocrystals of a porous coordination polymer {Fe(pz)[Pt(CN)₄]} (1) showing spin transition were prepared by the reverse micelle method, and the size-controlled mesocrystal 1 kept its porous property and magnetic bistability and exhibited higher guest-responsivity with switching the spin state in both solid and aqueous suspension states than the bulk 1.

This article is part of the themed collection: 2017 Journal of Materials Chemistry C HOT Papers

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Article information

DOI: https://doi.org/10.1039/C7TC00751E
Article type: Paper
Submitted: 18 Feb 2017
Accepted: 24 Mar 2017
First published: 30 Mar 2017

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J. Mater. Chem. C, 2017,5, 3706-3713

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Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers

A. Mishima, T. Koshiyama, J. A. Real and M. Ohba, J. Mater. Chem. C, 2017, 5, 3706 DOI: 10.1039/C7TC00751E

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Journal of Materials Chemistry C

Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers†

Abstract

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Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers

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