Issue 20, 2018
From the journal:

Chemical Communications

Expedient cobalt(ii)-catalyzed site-selective C7-arylation of indolines with arylboronic acids†

Pinaki Bhusan De,a   Sourav Pradhan,a   Sonbidya Banerjeea  and  Tharmalingam Punniyamurthy ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India
E-mail: tpunni@iitg.ernet.in

Abstract

Cobalt(II)-catalyzed pyrimidyl directing group-assisted C7 arylation of indolines with arylboronic acids has been developed using Mn(OAc)2·4H2O as an oxidant. The use of cobalt(II)–PCy3 as a catalyst and broad substrate scope are the important practical features.

Graphical abstract: Expedient cobalt(ii)-catalyzed site-selective C7-arylation of indolines with arylboronic acids

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Article information

DOI
https://doi.org/10.1039/C8CC00395E
Article type
Communication
Submitted
17 Jan 2018
Accepted
14 Feb 2018
First published
14 Feb 2018

Chem. Commun., 2018,54, 2494-2497

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Expedient cobalt(II)-catalyzed site-selective C7-arylation of indolines with arylboronic acids

P. B. De, S. Pradhan, S. Banerjee and T. Punniyamurthy, Chem. Commun., 2018, 54, 2494 DOI: 10.1039/C8CC00395E

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