Issue 26, 2018

Iron polypyridyl catalysts assembled on metal oxide semiconductors for photocatalytic hydrogen generation

Abstract

A series of Fe(III) complexes was recently reported that are active for photocatalytic hydrogen generation when paired with fluorescein and triethylamine. Herein we report an Fe(III) complex immobilized on TiO2 and SrTiO3 that is significantly more active than the homogeneous system, achieving up to 7800 turnovers in 31 hours.

Graphical abstract: Iron polypyridyl catalysts assembled on metal oxide semiconductors for photocatalytic hydrogen generation

Supplementary files

Article information

Article type
Communication
Submitted
18 Jan 2018
Accepted
07 Mar 2018
First published
07 Mar 2018

Chem. Commun., 2018,54, 3290-3293

Author version available

Iron polypyridyl catalysts assembled on metal oxide semiconductors for photocatalytic hydrogen generation

N. A. Race, W. Zhang, M. E. Screen, B. A. Barden and W. R. McNamara, Chem. Commun., 2018, 54, 3290 DOI: 10.1039/C8CC00453F

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