Issue 35, 2018
From the journal:

Chemical Communications

A giant 90-nucleus silver cluster templated by hetero-anions†

Jia-Wei Liu,‡a   Hai-Feng Su,‡c   Zhi Wang,a   Yan-An Li,b   Quan-Qin Zhao,a   Xing-Po Wang,a   Chen-Ho Tung,a   Di Sun ORCID logo *a  and  Lan-Sun Zhengc  

* Corresponding authors

a Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, People's Republic of China
E-mail: dsun@sdu.edu.cn
Fax: +86-531-88364218

b College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, People's Republic of China

c State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China

Abstract

A 90-nucleus silver cluster (SD/Ag38) cocapped by tBuC6H4S− and PhCOO− ligands was synthesized using hetero-anion template method. Single-crystal X-ray diffraction (SCXRD) revealed a 90-nucleus metallic dumbbell-like core constructed by two large W5O19@Ag38 heads sandwiching one slender (SO4)2@Ag14 waist. Both W5O198− and SO42− templates were in situ generated and synergistically induced the formation of the largest known anion-templated silver cluster. Although SD/Ag38 is emission-silent at room temperature, increasingly brighter near-infrared (NIR) emission at ca. 742 nm was detected on cooling from 293 to 93 K.

Graphical abstract: A giant 90-nucleus silver cluster templated by hetero-anions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8CC01767K
Article type
Communication
Submitted
04 Mar 2018
Accepted
29 Mar 2018
First published
03 Apr 2018

Chem. Commun., 2018,54, 4461-4464

Permissions

Request permissions

A giant 90-nucleus silver cluster templated by hetero-anions

J. Liu, H. Su, Z. Wang, Y. Li, Q. Zhao, X. Wang, C. Tung, D. Sun and L. Zheng, Chem. Commun., 2018, 54, 4461 DOI: 10.1039/C8CC01767K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements