Issue 50, 2018

Formation of coordination polymer glass by mechanical milling: dependence on metal ions and molecular doping for H+ conductivity

Abstract

Four isostructural coordination polymer crystals having different metal ions were synthesized and studied for ball milling-induced glass formation. Distinct glass formation was discussed from crystal structures. Doping of molecules for CP glass during the milling was demonstrated, and it resulted in tunable glass properties (Tg and Tc) and enhancement of anhydrous H+ conductivity.

Graphical abstract: Formation of coordination polymer glass by mechanical milling: dependence on metal ions and molecular doping for H+ conductivity

Supplementary files

Article information

Article type
Communication
Submitted
26 Mar 2018
Accepted
30 Apr 2018
First published
01 May 2018

Chem. Commun., 2018,54, 6859-6862

Author version available

Formation of coordination polymer glass by mechanical milling: dependence on metal ions and molecular doping for H+ conductivity

Y. Ohara, A. Hinokimoto, W. Chen, T. Kitao, Y. Nishiyama, Y. Hong, S. Kitagawa and S. Horike, Chem. Commun., 2018, 54, 6859 DOI: 10.1039/C8CC02399A

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