Issue 67, 2018
From the journal:

Chemical Communications

(Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes†‡

Eduard Spuling, ORCID logo §a   Nidhi Sharma,§bc   Ifor D. W. Samuel, ORCID logo *c   Eli Zysman-Colman ORCID logo *b  and  Stefan Bräse ORCID logo *ad  

* Corresponding authors

a Institute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76131 Karlsruhe, Germany
E-mail: braese@kit.edu
Fax: (+49)-721-6084-8581
Tel: (+49)-721-6084-2903

b Organic Semiconductor Centre, EaStCHEM School of Chemistry, University of St Andrews, St Andrews, Fife, UK
E-mail: eli.zysman-colman@st-andrews.ac.uk
Web: http://www.zysman-colman.com
Tel: +44 (0)1334 463826

c Organic Semiconductor Centre, SUPA, School of Physics and Astronomy, University of St Andrews, North Haugh, St Andrews, UK
E-mail: idws@st-andrews.ac.uk

d Institute of Toxicology and Genetics, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany

Abstract

The first examples of through-space conjugated thermally activated delayed fluorescence (TADF) emitters based on a [2.2]paracyclophane (PCP) skeleton with stacked (coplanar) donor–acceptor groups have been synthesized. The optoelectronic properties are studied by the relative configuration, cis (pseudo-geminal) and trans (pseudo-para), of the donor and acceptor groups.

Graphical abstract: (Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes

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Article information

DOI
https://doi.org/10.1039/C8CC04594A
Article type
Communication
Submitted
08 Jun 2018
Accepted
04 Jul 2018
First published
04 Jul 2018

Chem. Commun., 2018,54, 9278-9281

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(Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes

E. Spuling, N. Sharma, I. D. W. Samuel, E. Zysman-Colman and S. Bräse, Chem. Commun., 2018, 54, 9278 DOI: 10.1039/C8CC04594A

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