Issue 75, 2018

Revisiting complexation thermodynamics of transplutonium elements up to einsteinium

Abstract

Literature casts einsteinium as a departure from earlier transplutonium actinides, with a decrease in stability constants with aminopolycarboxylate ligands. This report studies transplutonium chemistry – including Am, Bk, Cf, and Es – with aminopolycarboxylate ligands. Es complexation follows similar thermodynamic and structural trends established by the earlier actinides, consistent with first-principle calculations.

Graphical abstract: Revisiting complexation thermodynamics of transplutonium elements up to einsteinium

Supplementary files

Article information

Article type
Communication
Submitted
02 Jul 2018
Accepted
28 Aug 2018
First published
29 Aug 2018

Chem. Commun., 2018,54, 10578-10581

Author version available

Revisiting complexation thermodynamics of transplutonium elements up to einsteinium

M. P. Kelley, N. P. Bessen, J. Su, M. Urban, S. I. Sinkov, G. J. Lumetta, E. R. Batista, P. Yang and J. C. Shafer, Chem. Commun., 2018, 54, 10578 DOI: 10.1039/C8CC05230A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements