Issue 77, 2018
From the journal:

Chemical Communications

Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array†

Irene Ling, ORCID logo *ab   Harshita Kumari, ORCID logo c   Marzieh Mirzamani, ORCID logo c   Alexandre N. Sobolev,d   Christopher J. Garvey,e   Jerry L. Atwood ORCID logo f  and  Colin L. Raston ORCID logo *b  

* Corresponding authors

a School of Science, Monash University Malaysia, Jalan Lagoon Selatan, Bandar Sunway, Malaysia
E-mail: ireneling@monash.edu

b Centre for NanoScale Science and Technology, School of Chemical and Physical Sciences, Flinders University, Bedford Park, Australia

c James L. Winkle College of Pharmacy, University of Cincinnati, 231 Albert Sabin Way, MSB # 3109C, Cincinnati, OH 45267, USA

d School of Molecular Sciences, M310, The University of Western Australia, 35 Stirling Highway, Perth, WA 6009, Australia

e Australian Nuclear Science and Technology Organization, New Illawara Road, Lucas Heights, NSW, Australia

f Department of Chemistry, University of Missouri, 601 South College Avenue, Columbia, MO 65211, USA

Abstract

We report on the assembly of three-fold axially compressed icosahedral arrays of the bowl shaped p-sulfonatocalix[4]arene molecules in the solid-state, intricately bound to dipicolinate and yttrium(III) ions, with the compression reflected in Hirshfeld surface analyses. Solution studies show dissolution of the icosahedra intact, but with a geometrical rearrangement to regular icosahedra.

Graphical abstract: Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

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Article information

DOI
https://doi.org/10.1039/C8CC05650A
Article type
Communication
Submitted
12 Jul 2018
Accepted
14 Aug 2018
First published
14 Aug 2018

Chem. Commun., 2018,54, 10824-10827

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Phase dependent structural perturbation of a robust multicomponent assembled icosahedral array

I. Ling, H. Kumari, M. Mirzamani, A. N. Sobolev, C. J. Garvey, J. L. Atwood and C. L. Raston, Chem. Commun., 2018, 54, 10824 DOI: 10.1039/C8CC05650A

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