Issue 85, 2018
From the journal:

Chemical Communications

Consecutive one-/two-step relaxation transformations of single-molecule magnets via coupling dinuclear dysprosium compounds with chloride bridges†

Haiquan Tian, ORCID logo *a   Bao-Lin Wang,*b   Jing Lu,a   Hou-Ting Liu,a   Jianhui Su,a   Dacheng Lia  and  Jianmin Dou ORCID logo *a  

* Corresponding authors

a Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, P. R. China
E-mail: dougroup@163.com, tianhaiquan@lcu.edu.cn

b Jiangsu Key Laboratory for NSLSCS, School of Physical Science and Technology, Nanjing Normal University, Nanjing 210023, P. R. China
E-mail: blwang@njnu.edu.cn

Abstract

The double chloride-bridged dimer of a dinuclear dysprosium(III) single-molecule magnet (SMM) was successfully isolated by assembling centrosymmetric dinuclear Dy2 SMMs. Such structural transformation involves the generation and cleavage of chloride bridges and leads to consecutive transformations of one- and two-step slow relaxation of magnetization.

Graphical abstract: Consecutive one-/two-step relaxation transformations of single-molecule magnets via coupling dinuclear dysprosium compounds with chloride bridges

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Article information

DOI
https://doi.org/10.1039/C8CC06699J
Article type
Communication
Submitted
17 Aug 2018
Accepted
02 Oct 2018
First published
02 Oct 2018

Chem. Commun., 2018,54, 12105-12108

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Consecutive one-/two-step relaxation transformations of single-molecule magnets via coupling dinuclear dysprosium compounds with chloride bridges

H. Tian, B. Wang, J. Lu, H. Liu, J. Su, D. Li and J. Dou, Chem. Commun., 2018, 54, 12105 DOI: 10.1039/C8CC06699J

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