Cationic indium complexes for the copolymerization of functionalized epoxides with cyclic ethers and lactide

Abstract

We report the first example of discrete cationic indium complexes for the copolymerization of epoxides, cyclic ethers, and lactide. [SalenIn][SbF₆] in particular proved to be a highly active catalyst for the homo-polymerization of functionalized epoxides and their copolymerization with other cyclic ethers THF, oxetane and oxepane. This catalyst also proved competent in the polymerization of epichlorohydrin and lactide, forming copolymers with good activity and control. Investigation of the role of counteranions and solvent donors on the kinetics of polymerization of epoxides revealed a subtle effect of solvents on initiation rates.