Issue 11, 2019
From the journal:

Chemical Communications

Modulating the expression of chirality in a mechanically chiral rotaxane†

Charles E. Gell, ORCID logo a   Timur A. McArdle-Ismaguilov ORCID logo ‡a  and  Nicholas H. Evans ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Lancaster University, Lancaster, LA1 4YB, UK
E-mail: n.h.evans@lancaster.ac.uk

Abstract

The expression of mechanical chirality by a hydrogen bond templated rotaxane, as detected by 1H NMR spectroscopy, may be modulated by affecting the co-conformational behaviour of the rotaxane through varying solvent or by addition of acid and base.

Graphical abstract: Modulating the expression of chirality in a mechanically chiral rotaxane

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Article information

DOI
https://doi.org/10.1039/C8CC10044F
Article type
Communication
Submitted
19 Dec 2018
Accepted
10 Jan 2019
First published
14 Jan 2019
This article is Open Access
Creative Commons BY license

Chem. Commun., 2019,55, 1576-1579

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Modulating the expression of chirality in a mechanically chiral rotaxane

C. E. Gell, T. A. McArdle-Ismaguilov and N. H. Evans, Chem. Commun., 2019, 55, 1576 DOI: 10.1039/C8CC10044F

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