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Here, we report the first direct amination of phenol with ammonia into primary anilines in the liquid phase. For this, Pd/C was demonstrated to be the most suitable catalyst. Optimization of the reaction parameters resulted in very selective and sustainable production of primary anilines with yields of up to 95%.
T. Cuypers, P. Tomkins and D. E. De Vos, Catal. Sci. Technol., 2018, 8, 2519 DOI: 10.1039/C8CY00193F
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