Issue 24, 2018

Hybrid organic–inorganic connectivity of NdIII(pyrazine-N,N′-dioxide)[CoIII(CN)6]3− coordination chains for creating near-infrared emissive Nd(iii) showing field-induced slow magnetic relaxation

Abstract

A near-infrared emissive and magnetically anisotropic Nd(III) complex is formed within a hybrid organic–inorganic {[NdIII(pzdo)(H2O)4][CoIII(CN)6]}·0.5(pzdo)·4H2O (1) (pzdo = pyrazine-N,N′-dioxide) ladder chain built of coexisting Nd–pzdo–Nd and Nd–NC–Co molecular bridges. 1 reveals two NdIII-centered properties, a field-induced slow magnetic relaxation of a single-ion origin with a thermal energy barrier of ΔE/kB = 51(2) K at Hdc = 1 kOe, and a near-infrared fluorescence sensitized by organic and inorganic linkers.

Graphical abstract: Hybrid organic–inorganic connectivity of NdIII(pyrazine-N,N′-dioxide)[CoIII(CN)6]3− coordination chains for creating near-infrared emissive Nd(iii) showing field-induced slow magnetic relaxation

Supplementary files

Article information

Article type
Communication
Submitted
13 Apr 2018
Accepted
10 May 2018
First published
11 May 2018

Dalton Trans., 2018,47, 7870-7874

Hybrid organic–inorganic connectivity of NdIII(pyrazine-N,N′-dioxide)[CoIII(CN)6]3− coordination chains for creating near-infrared emissive Nd(III) showing field-induced slow magnetic relaxation

S. Chorazy, T. Charytanowicz, J. Wang, S. Ohkoshi and B. Sieklucka, Dalton Trans., 2018, 47, 7870 DOI: 10.1039/C8DT01464G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements