Issue 27, 2018
From the journal:

Dalton Transactions

Pseudotetrahedral cobalt(ii) complexes with PNP-ligands showing uniaxial magnetic anisotropy†

Yuan-Qi Zhai,a   Yi-Fei Denga  and  Yan-Zhen Zheng ORCID logo *a  

* Corresponding authors

a Frontier Institute of Science and Technology (FIST), State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis of Condensed Matter, Xi'an Key Laboratory of Sustainable Energy and Materials Chemistry and School of Science, Xi'an Jiaotong University, 99 Yanxiang Road, Xi'an, Shaanxi 710054, P. R. China
E-mail: zheng.yanzhen@xjtu.edu.cn

Abstract

Two mononuclear pseudotetrahedral cobalt(II) complexes with the formula Co(PNP)X2, where X = Cl (1) or X = SCN (2) and PNP = bis(2-(diphenylphosphaneyl)-4-methylphenyl)amine, have been synthesised. Magnetic and high-frequency/field electron paramagnetic resonance (HF-EPR) spectroscopy and ab initio calculation studies reveal that both complexes show uniaxial magnetic anisotropy.

Graphical abstract: Pseudotetrahedral cobalt(ii) complexes with PNP-ligands showing uniaxial magnetic anisotropy

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Article information

DOI
https://doi.org/10.1039/C8DT01683F
Article type
Communication
Submitted
27 Apr 2018
Accepted
05 Jun 2018
First published
06 Jun 2018

Dalton Trans., 2018,47, 8874-8878

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Pseudotetrahedral cobalt(II) complexes with PNP-ligands showing uniaxial magnetic anisotropy

Y. Zhai, Y. Deng and Y. Zheng, Dalton Trans., 2018, 47, 8874 DOI: 10.1039/C8DT01683F

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