Issue 38, 2018
From the journal:

Dalton Transactions

Protonation and water exchange kinetics in sandwich polyoxometalates†

C. André Ohlin ORCID logo *a  and  Magda Pascual-Borràsa  

* Corresponding authors

a Department of Chemistry, Umeå University, Umeå, Sweden
E-mail: andre.ohlin@umu.se
Web: http://moleculargeo.chem.umu.se

Abstract

Density functional theory is used to explore the locus and consequences of protonation in [Zn4(HO)2(PW9O34)2]10−. The results are used to explain recent observations regarding the contrasting pH effects on the water-ligand exchange in [Mn4(H2O)2(P2W15O56)2]16− and [Co4(H2O)2(P2W15O56)2]16−, and the general effect of protonation on solvent exchange in metal oxides is discussed.

Graphical abstract: Protonation and water exchange kinetics in sandwich polyoxometalates

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Article information

DOI
https://doi.org/10.1039/C8DT02342E
Article type
Paper
Submitted
07 Jun 2018
Accepted
30 Aug 2018
First published
05 Sep 2018
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2018,47, 13602-13607

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Protonation and water exchange kinetics in sandwich polyoxometalates

C. A. Ohlin and M. Pascual-Borràs, Dalton Trans., 2018, 47, 13602 DOI: 10.1039/C8DT02342E

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