Methyl camouflage in the ten-vertex closo-dicarbaborane(10) series. Isolation of closo-1,6-R2C2B8Me8 (R = H and Me) and their monosubstituted analogues

Mario Bakardjiev; Oleg L. Tok; Aleš Růžička; Zdeňka Růžičková; Josef Holub; Drahomír Hnyk; Zbyněk Špalt; Jindřich Fanfrlík; Bohumil Štíbr

doi:10.1039/C8DT02586J

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Methyl camouflage in the ten-vertex closo-dicarbaborane(10) series. Isolation of closo-1,6-R₂C₂B₈Me₈ (R = H and Me) and their monosubstituted analogues†

Mario Bakardjiev,^a Oleg L. Tok,^a Aleš Růžička,^b Zdeňka Růžičková,^b Josef Holub,^a Drahomír Hnyk,

^a Zbyněk Špalt,^a Jindřich Fanfrlík

^c and Bohumil Štíbr

*^a

Author affiliations

* Corresponding authors

^a Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Husinec-Řež 1001, Czech Republic

^b Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentská 573, 532 10 Pardubice, Czech Republic

^c Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo nám. 2, 166 10 Prague 6, Czech Republic

Abstract

Reported are procedures leading to the first types of methyl camouflaged dicarbadecaboranes with fewer than eleven vertices. The compounds contain the closo-1,6-C₂B₈ scaffolding inside the egg-shaped hepta – decamethyl sheath, which imparts unusually high air and solvolytic stability to all of these compounds.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C8DT02586J
Article type: Paper
Submitted: 25 Jun 2018
Accepted: 17 Jul 2018
First published: 23 Jul 2018
This article is Open Access

Download Citation

Dalton Trans., 2018,47, 11070-11076

Permissions

Request permissions

Methyl camouflage in the ten-vertex closo-dicarbaborane(10) series. Isolation of closo-1,6-R₂C₂B₈Me₈ (R = H and Me) and their monosubstituted analogues

M. Bakardjiev, O. L. Tok, A. Růžička, Z. Růžičková, J. Holub, D. Hnyk, Z. Špalt, J. Fanfrlík and B. Štíbr, Dalton Trans., 2018, 47, 11070 DOI: 10.1039/C8DT02586J

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Dalton Transactions