Ge(II) cation catalyzed hydroboration of aldehydes and ketones

Soumen Sinhababu; Dharmendra Singh; Mahendra Kumar Sharma; Rahul Kumar Siwatch; Pritam Mahawar; Selvarajan Nagendran

doi:10.1039/C8DT05121F

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Ge(ii) cation catalyzed hydroboration of aldehydes and ketones†

Soumen Sinhababu,

‡^a Dharmendra Singh,

‡^a Mahendra Kumar Sharma,

^a Rahul Kumar Siwatch,

^a Pritam Mahawar

^a and Selvarajan Nagendran

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016, India
E-mail: sisn@chemistry.iitd.ac.in

Abstract

Well-defined germylene cations [(i-Bu)₂ATI]GeOTf (4) and [(i-Bu)₂ATIGe][GaCl₄] (5) are isolated, and the catalytic utility of compound 4 for the hydroboration of a variety of aldehydes and ketones is reported (ATI = aminotroponiminate).

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DOI: https://doi.org/10.1039/C8DT05121F
Article type: Communication
Submitted: 26 Dec 2018
Accepted: 07 Feb 2019
First published: 07 Feb 2019

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Dalton Trans., 2019,48, 4094-4100

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Ge(II) cation catalyzed hydroboration of aldehydes and ketones

S. Sinhababu, D. Singh, M. K. Sharma, R. K. Siwatch, P. Mahawar and S. Nagendran, Dalton Trans., 2019, 48, 4094 DOI: 10.1039/C8DT05121F

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Dalton Transactions

Ge(ii) cation catalyzed hydroboration of aldehydes and ketones†

Abstract

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Ge(II) cation catalyzed hydroboration of aldehydes and ketones

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