Halogen-bond driven self-assembly of triangular macrocycles

Patrick M. J. Szell; Antti Siiskonen; Luca Catalano; Gabriella Cavallo; Giancarlo Terraneo; Arri Priimagi; David L. Bryce; Pierangelo Metrangolo

doi:10.1039/C8NJ00759D

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Halogen-bond driven self-assembly of triangular macrocycles†

Patrick M. J. Szell,^a Antti Siiskonen,^b Luca Catalano,^c Gabriella Cavallo,

*^c Giancarlo Terraneo,

^c Arri Priimagi,

^b David L. Bryce

^a and Pierangelo Metrangolo

*^c

Author affiliations

* Corresponding authors

^a Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, 10 Marie Curie Private, Ontario K1N 6N5, Canada

^b Laboratory of Chemistry and Bioengineering, Tampere University of Technology, P.O. Box 541, FI-33101 Tampere, Finland

^c Laboratory of Supramolecular and Bio-Nanomaterials (SupraBioNanoLab), Department of Chemistry, Materials, and Chemical Engineering “Giulio Natta”, Politecnico di Milano, Via Luigi Mancinelli 7, 20131 Milano, Italy
E-mail: gabriella.cavallo@polimi.it, pierangelo.metrangolo@polimi.it

Abstract

2-Iodoethynylpyridine and 2-iodoethynyl-1-methyl-imidazole self-assemble under halogen-bonding control into discrete macrocycles, viz. supramolecular triangles.

This article is part of the themed collection: The halogen bond: a new avenue in recognition and self-assembly

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Article information

DOI: https://doi.org/10.1039/C8NJ00759D
Article type: Letter
Submitted: 14 Feb 2018
Accepted: 01 Mar 2018
First published: 02 Mar 2018

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New J. Chem., 2018,42, 10467-10471

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Halogen-bond driven self-assembly of triangular macrocycles

P. M. J. Szell, A. Siiskonen, L. Catalano, G. Cavallo, G. Terraneo, A. Priimagi, D. L. Bryce and P. Metrangolo, New J. Chem., 2018, 42, 10467 DOI: 10.1039/C8NJ00759D

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New Journal of Chemistry

Halogen-bond driven self-assembly of triangular macrocycles†

Abstract

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Halogen-bond driven self-assembly of triangular macrocycles

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