Synthesis of copolymers with an exact alternating sequence using the cationic polymerization of pre-sequenced monomers

Chengke Qu; Zhenhua Li; Junpo He

doi:10.1039/C8PY00626A

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Synthesis of copolymers with an exact alternating sequence using the cationic polymerization of pre-sequenced monomers†

Chengke Qu,^a Zhenhua Li

^b and Junpo He

*^a

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* Corresponding authors

^a State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, China
E-mail: jphe@fudan.edu.cn

^b Department of Chemistry, Fudan University, Shanghai, China

Abstract

Alternating copolymers composed of styrene/methyl vinyl ether derived repeating units and styrene/vinyl alcohol based repeating units were synthesized through the cationic polymerization of 1,3-butadiene derivatives and the subsequent hydrogenation reaction. The microstructure of the resulting polymers was characterized by NMR spectroscopy. The effect of an alternating sequence on the fluorescence emissions of the products was investigated.

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Article information

DOI: https://doi.org/10.1039/C8PY00626A
Article type: Communication
Submitted: 24 Apr 2018
Accepted: 04 Jun 2018
First published: 05 Jun 2018

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Polym. Chem., 2018,9, 3455-3460

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Synthesis of copolymers with an exact alternating sequence using the cationic polymerization of pre-sequenced monomers

C. Qu, Z. Li and J. He, Polym. Chem., 2018, 9, 3455 DOI: 10.1039/C8PY00626A

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Polymer Chemistry

Synthesis of copolymers with an exact alternating sequence using the cationic polymerization of pre-sequenced monomers†

Abstract

Supplementary files

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Synthesis of copolymers with an exact alternating sequence using the cationic polymerization of pre-sequenced monomers

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