Issue 38, 2019

Crystal melting and glass formation in copper thiocyanate based coordination polymers

Abstract

Crystal melting and glass formation of coordination polymers (CPs) and metal–organic frameworks (MOFs) are rare thermal events. To expand the library of melting CP/MOFs, we utilized anti-crystal engineering in ionic liquids to construct CPs. A combination of Cu+ and 4,4′-bipyridin-1-ium derivatives afforded four melting CPs showing stable liquid and glassy states.

Graphical abstract: Crystal melting and glass formation in copper thiocyanate based coordination polymers

Supplementary files

Article information

Article type
Communication
Submitted
19 Mar 2019
Accepted
10 Apr 2019
First published
10 Apr 2019

Chem. Commun., 2019,55, 5455-5458

Author version available

Crystal melting and glass formation in copper thiocyanate based coordination polymers

S. S. Nagarkar, H. Kurasho, N. T. Duong, Y. Nishiyama, S. Kitagawa and S. Horike, Chem. Commun., 2019, 55, 5455 DOI: 10.1039/C9CC02172H

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