Issue 49, 2019
From the journal:

Chemical Communications

“Normal” and “reverse” spin crossover induced by two different structural events in iron(ii) coordination polymer†

Marek Weselski,a   Maria Książek,b   Pamela Mess,a   Joachim Kuszb  and  Robert Bronisz ORCID logo *a  

* Corresponding authors

a Faculty of Chemistry, University of Wrocław, F. Joliot-Curie 14, Wrocław, Poland
E-mail: robert.bronisz@chem.uni.wroc.pl

b University of Silesia, 75 Pułku Piechoty 1, 41-500 Chorzów, Poland

Abstract

In [Fe(ebbtr)2(CH3CN)2](CF3SO3)2·4CH3CN spin crossover is associated with the occurrence of “normal” and “reverse” hysteresis loops separated by a region of stable HS form. This results from trans–trans → gauche–trans conformational changes of ebbtr molecules and anion reorientation, which occur in different ways during cooling and during heating.

Graphical abstract: “Normal” and “reverse” spin crossover induced by two different structural events in iron(ii) coordination polymer

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Article information

DOI
https://doi.org/10.1039/C9CC02755F
Article type
Communication
Submitted
09 Apr 2019
Accepted
14 May 2019
First published
14 May 2019

Chem. Commun., 2019,55, 7033-7036

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“Normal” and “reverse” spin crossover induced by two different structural events in iron(II) coordination polymer

M. Weselski, M. Książek, P. Mess, J. Kusz and R. Bronisz, Chem. Commun., 2019, 55, 7033 DOI: 10.1039/C9CC02755F

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