Issue 75, 2019
From the journal:

Chemical Communications

Enantioselective organocatalytic activation of vinylidene–quinone methides (VQMs)

Jean Rodriguez ORCID logo *a  and  Damien Bonne ORCID logo *a  

* Corresponding authors

a Aix Marseille Université, CNRS, Centrale Marseille, iSm2, Marseille, France
E-mail: damien.bonne@univ-amu.fr, jean.rodriguez@univ-amu.fr

Abstract

Vinylidene–quinone methides (VQMs) are highly electrophilic chiral reagents that can be generated in situ from 2-(phenylethynyl)phenols. They were characterized for the first time in 2012 but their enantioselective organocatalytic activation was addressed only very recently. Their specific reactivity has revealed innovative strategies notably for the control of axial chirality.

Graphical abstract: Enantioselective organocatalytic activation of vinylidene–quinone methides (VQMs)

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Article information

DOI
https://doi.org/10.1039/C9CC05097C
Article type
Highlight
Submitted
03 Jul 2019
Accepted
29 Aug 2019
First published
29 Aug 2019

Chem. Commun., 2019,55, 11168-11170

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Enantioselective organocatalytic activation of vinylidene–quinone methides (VQMs)

J. Rodriguez and D. Bonne, Chem. Commun., 2019, 55, 11168 DOI: 10.1039/C9CC05097C

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