Issue 67, 2019
From the journal:

Chemical Communications

A square antiprism dysprosium single-ion magnet with an energy barrier over 900 K†

Sukhen Bala,a   Guo-Zhang Huang, ORCID logo a   Ze-Yu Ruan,a   Si-Guo Wu,a   Yang Liu,a   Long-Fei Wang,a   Jun-Liang Liu ORCID logo *a  and  Ming-Liang Tong ORCID logo *a  

* Corresponding authors

a Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China
E-mail: liujliang5@mail.sysu.edu.cn, tongml@mail.sysu.edu.cn

Abstract

Herein we report a stable and high-performance Dy(III) single-ion magnet (SIM) showing an energy barrier of 944 K under zero dc field, with an open hysteresis loop up to 6 K. To the best of our knowledge, this is the highest energy barrier for a square antiprism as well as phosphine oxide based Dy-SIMs, reported so far.

Graphical abstract: A square antiprism dysprosium single-ion magnet with an energy barrier over 900 K

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Article information

DOI
https://doi.org/10.1039/C9CC05135J
Article type
Communication
Submitted
04 Jul 2019
Accepted
24 Jul 2019
First published
24 Jul 2019

Chem. Commun., 2019,55, 9939-9942

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A square antiprism dysprosium single-ion magnet with an energy barrier over 900 K

S. Bala, G. Huang, Z. Ruan, S. Wu, Y. Liu, L. Wang, J. Liu and M. Tong, Chem. Commun., 2019, 55, 9939 DOI: 10.1039/C9CC05135J

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