Issue 75, 2019

Visible light photocatalytic asymmetric synthesis of pyrrolo[1,2-a]indoles via intermolecular [3+2] cycloaddition

Abstract

The intermolecular diastereoselective and enantioselective synthesis of pyrrolo[1,2-a]indoles is developed through a [3+2] cycloaddition between silyl-indole derivatives and α,β-unsaturated N-acyl oxazolidinones by merging photocatalysis and Lewis acid catalysis.

Graphical abstract: Visible light photocatalytic asymmetric synthesis of pyrrolo[1,2-a]indoles via intermolecular [3+2] cycloaddition

Supplementary files

Article information

Article type
Communication
Submitted
26 Jul 2019
Accepted
27 Aug 2019
First published
27 Aug 2019

Chem. Commun., 2019,55, 11303-11306

Visible light photocatalytic asymmetric synthesis of pyrrolo[1,2-a]indoles via intermolecular [3+2] cycloaddition

A. Casado-Sánchez, P. Domingo-Legarda, S. Cabrera and J. Alemán, Chem. Commun., 2019, 55, 11303 DOI: 10.1039/C9CC05838A

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