Issue 80, 2019

Accordion and layer-sliding motion to produce anomalous thermal expansion behaviour in 2D-coordination polymers

Abstract

Solvent-free (1) and solvated (2) 2D-coordination polymers have been synthesised by varying the amount of solvent during crystallisation. 1 undergoes a unique accordion motion of 2D zig-zag interwoven layers whereas 2 experiences layer-sliding within 2D layers to produce anomalous thermal expansion behaviour.

Graphical abstract: Accordion and layer-sliding motion to produce anomalous thermal expansion behaviour in 2D-coordination polymers

Supplementary files

Article information

Article type
Communication
Submitted
26 Aug 2019
Accepted
07 Sep 2019
First published
09 Sep 2019

Chem. Commun., 2019,55, 12048-12051

Accordion and layer-sliding motion to produce anomalous thermal expansion behaviour in 2D-coordination polymers

P. Lama, A. Hazra and L. J. Barbour, Chem. Commun., 2019, 55, 12048 DOI: 10.1039/C9CC06634A

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