An Fe(III)-doped coordination polymer of Mn13-clusters with improved activity for the oxygen reduction reaction

Tian Wen; Wolfgang Schmitt; Lei Zhang

doi:10.1039/C9DT00199A

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An Fe(iii)-doped coordination polymer of Mn₁₃-clusters with improved activity for the oxygen reduction reaction†

Tian Wen,^a Wolfgang Schmitt

^b and Lei Zhang

*^a

Author affiliations

* Corresponding authors

^a School of Chemistry, The University of Melbourne, Parkville, Victoria 3010, Australia
E-mail: lei.zhang1@unimelb.edu.au

^b School of Chemistry & CRANN, University of Dublin, Trinity College, Dublin 2, Ireland

Abstract

Fe(III) dopants have been introduced into a porous coordination polymer of Mn₁₃-clusters to form composite materials. The resulting Fe@Mn₁₃-polymer showed enhanced oxygen reduction reaction (ORR) activity, making it a low-cost and noble-metal-free ORR electrocatalyst.

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Article information

DOI: https://doi.org/10.1039/C9DT00199A
Article type: Communication
Submitted: 15 Jan 2019
Accepted: 12 Mar 2019
First published: 13 Mar 2019

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Dalton Trans., 2019,48, 4794-4797

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An Fe(III)-doped coordination polymer of Mn₁₃-clusters with improved activity for the oxygen reduction reaction

T. Wen, W. Schmitt and L. Zhang, Dalton Trans., 2019, 48, 4794 DOI: 10.1039/C9DT00199A

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Dalton Transactions