Issue 37, 2019

Sub-nanometer Cu(i) clusters: coordination-modulated (Se vs. S) atom-packing mode and emission

Abstract

Herein, the ligands’ effect in Cu(I) clusters was initially explored. The results demonstrate that the Se atom possesses more coordination modes with Cu (μ2, μ3, μ4, μ6) than S, which significantly modulates the atom-packing mode of Cu(I) clusters. Importantly, this also endows these clusters with different temperature-dependent luminescent behaviours.

Graphical abstract: Sub-nanometer Cu(i) clusters: coordination-modulated (Se vs. S) atom-packing mode and emission

Supplementary files

Article information

Article type
Communication
Submitted
15 Jul 2019
Accepted
27 Aug 2019
First published
27 Aug 2019

Dalton Trans., 2019,48, 13921-13924

Sub-nanometer Cu(I) clusters: coordination-modulated (Se vs. S) atom-packing mode and emission

F. Ke, Y. Song, H. Li, C. Zhou, Y. Du and M. Zhu, Dalton Trans., 2019, 48, 13921 DOI: 10.1039/C9DT02908G

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