Issue 13, 2019

H2O-controlled selective thiocyanation and alkenylation of ketene dithioacetals under electrochemical oxidation

Abstract

Efficient and H2O-controlled selective thiocyanation and alkenylation of internal olefins, to afford tetrasubstituted olefins under electrochemical oxidation, has been successfully developed. This transformation can present a critical feature wherein neither exogenous oxidants nor catalysts are required. Notably, such an electrochemical oxidation-based synthetic strategy exhibits excellent tolerance towards functional groups and can be easily scaled up with good efficiency.

Graphical abstract: H2O-controlled selective thiocyanation and alkenylation of ketene dithioacetals under electrochemical oxidation

Supplementary files

Article information

Article type
Paper
Submitted
25 Apr 2019
Accepted
23 May 2019
First published
23 May 2019

Green Chem., 2019,21, 3597-3601

H2O-controlled selective thiocyanation and alkenylation of ketene dithioacetals under electrochemical oxidation

J. Wen, L. Zhang, X. Yang, C. Niu, S. Wang, W. Wei, X. Sun, J. Yang and H. Wang, Green Chem., 2019, 21, 3597 DOI: 10.1039/C9GC01351B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements