Issue 32, 2019

Photo-induced copper-RDRP in continuous flow without external deoxygenation

Abstract

Photo-induced Cu-RDRP of acrylates in a continuous flow reactor without the need for deoxygenation or externally added reagents. Optimization of the catalyst concentration and the flow rate/residence time leads to well-defined polyacrylates with controlled molecular weights, excellent initiator efficiency, high end-group fidelity polymers and product uniformity. A multifunctional initiator was also used to demonstrate the versatility of the system.

Graphical abstract: Photo-induced copper-RDRP in continuous flow without external deoxygenation

Supplementary files

Article information

Article type
Communication
Submitted
27 Jun 2019
Accepted
06 Jul 2019
First published
19 Jul 2019
This article is Open Access
Creative Commons BY-NC license

Polym. Chem., 2019,10, 4402-4406

Photo-induced copper-RDRP in continuous flow without external deoxygenation

A. Marathianos, E. Liarou, A. Anastasaki, R. Whitfield, M. Laurel, A. M. Wemyss and D. M. Haddleton, Polym. Chem., 2019, 10, 4402 DOI: 10.1039/C9PY00945K

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