Issue 11, 2019

Luminescent perovskites: recent advances in theory and experiments

Abstract

Perovskites form an important and enormous class of inorganic compounds. Recently, perovskite materials have attracted extensive research interest owing to their excellent optoelectronic properties. Deep insights into the relationships between the crystal structure, electronic structure and properties play an important role in the development of new functional materials and high-performance devices. In this review, after a brief introduction, we first discuss the crystal structure and crystal chemistry of perovskites according to their three classes: standard perovskites, low-dimensional perovskites and perovskite-like halides. Next, the electronic structure and luminescence from different physical origins are presented. Then, we present a survey on the design, synthesis and luminescence properties of different perovskites, including halide perovskites, oxide perovskites, and lanthanide- or transition metal-doped perovskites, also including dimension-different perovskites (3D, 2D, 1D and quantum dots). We also summarize the strategies for improving the photoluminescence quantum yield (PLQY) and chemical stability, including by surface passivation, encapsulation and doping. Finally, we review their applications and give a brief outlook.

Graphical abstract: Luminescent perovskites: recent advances in theory and experiments

Article information

Article type
Review Article
Submitted
26 Jun 2019
Accepted
16 Aug 2019
First published
19 Aug 2019

Inorg. Chem. Front., 2019,6, 2969-3011

Luminescent perovskites: recent advances in theory and experiments

Z. Song, J. Zhao and Q. Liu, Inorg. Chem. Front., 2019, 6, 2969 DOI: 10.1039/C9QI00777F

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