Issue 7, 2019
From the journal:

Organic Chemistry Frontiers

Reactions of 2-aza-21-carbaporphyrin with aniline derivatives†

Demin Ren,a   Bin Liu, ORCID logo b   Xiaofang Li, ORCID logo *b   Sebastian Koniarz, ORCID logo c   Miłosz Pawlicki ORCID logo c  and  Piotr J. Chmielewski ORCID logo *c  

* Corresponding authors

a College of Science, Hunan Agricultural University, Changsha 410128, P. R. China

b Key Laboratory of Theoretical Organic Chemistry and Functional Molecules, Ministry of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China
E-mail: lixiaofang@iccas

c Department of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50 383 Wrocław, Poland
E-mail: piotr.chmielewski@chem.uni.wroc.pl

Abstract

Regioselective azotization or bis(amination) products of the title porphyrinoid were achieved in one-pot one-step syntheses under mild conditions using a selection of aromatic amines and isoamyl nitrite or p-chloranil, respectively. Structures, tautomery, chirality as well as spectroscopic and redox properties of the new systems were discussed.

Graphical abstract: Reactions of 2-aza-21-carbaporphyrin with aniline derivatives

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Article information

DOI
https://doi.org/10.1039/C9QO00024K
Article type
Research Article
Submitted
07 Jan 2019
Accepted
11 Feb 2019
First published
12 Feb 2019

Org. Chem. Front., 2019,6, 908-918

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Reactions of 2-aza-21-carbaporphyrin with aniline derivatives

D. Ren, B. Liu, X. Li, S. Koniarz, M. Pawlicki and P. J. Chmielewski, Org. Chem. Front., 2019, 6, 908 DOI: 10.1039/C9QO00024K

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