The monomeric diaminophosphinoboranes readily react with CO2 under mild conditions to cleanly form products of the general formula 
in the absence of a catalyst. The isolated products from the CO2-phosphinoboration were fully characterized by NMR spectroscopy, IR spectroscopy, and X-ray diffraction. The mechanism of CO2 phosphinoboration with diaminophosphinoboranes was elucidated by DFT calculations.
N. Szynkiewicz, A. Ordyszewska, J. Chojnacki and R. Grubba, RSC Adv., 2019, 9, 27749 DOI: 10.1039/C9RA06638A
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