Issue 6, 1996

Anion selective recognition and optical/electrochemical sensing by novel transition-metal receptor systems

Abstract

Appropriately designed charged or neutral redox- and/or photo-active transition-metal organometallic and coordination receptor systems can selectively recognise and sense anionic guest species by electrochemical and/or optical methodologies. The topological positioning of the transition-metal Lewis-acid centres and of the ubiquitous hydrogen-bonding functionalities, such as amide (CO–NH) groups, dictates the anion selectivity trend and sensing proficiency the particular receptor displays.

Article information

Article type
Paper

Chem. Commun., 1996, 689-696

Anion selective recognition and optical/electrochemical sensing by novel transition-metal receptor systems

P. D. Beer, Chem. Commun., 1996, 689 DOI: 10.1039/CC9960000689

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