SCHEDULED MAINTENANCE
The compound (Me2Nme2Si)3CH is readily metallated by MeLi in THF to give the linear-polymeric {(Me2Nme2Si)3Cli}∞, in which two of the N atoms in each planar carbanionic unit (Me2Nme2Si)3C– are attached to one lithium atom and the remaining N atom to another Li atom; each Li shows planar three-coordination.
F. Adam, C. Eaborn, P. B. Hitchcock and J. D. Smith, Chem. Commun., 1996, 741 DOI: 10.1039/CC9960000741
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