Poly(hexene) with very high molecular weight is produced at 250 MPa (2500 atm) with (C5HMe4)2HfCl2–methyl aluminoxane (MAO) as catalyst; the dependence of the polymerization on the reaction pressure (0.1 MPa–1.5 GPa) and the substituent pattern of a zirconocene catalyst is described.
A. Fries, T. Mise, A. Matsumoto, H. Ohmori and Y. Wakatsuki, Chem. Commun., 1996, 783 DOI: 10.1039/CC9960000783
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