Issue 17, 1996

A highly active alkane dehydrogenation catalyst: stabilization of dihydrido rhodium and iridium complexes by a P–C–P pincer ligand

Abstract

The novel P–C–P pincer complex, [IrH2{C6H3(CH22PBut2)2}] has long-term stability and 200 ° C and catalyses the transfer dehydrogenation of cyclooctnane to cyclooctene at the rate of 12 turnovers min1 min–1.

Article information

Article type
Paper

Chem. Commun., 1996, 2083-2084

A highly active alkane dehydrogenation catalyst: stabilization of dihydrido rhodium and iridium complexes by a P–C–P pincer ligand

M. Gupta, C. Hagen, R. J. Flesher, W. C. Kaska and C. M. Jensen, Chem. Commun., 1996, 2083 DOI: 10.1039/CC9960002083

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