Issue 19, 1996

Definitive crystal structures of ortho-, meta- and para-carboranes: supramolecular structures directed solely by C–H⋯O hydrogen bonding to hmpa (hmpa = hexamethylphosphoramide)

Abstract

Cocrystallisation of ortho-meta- and para-carboranes with hmpa (hexamethylphosphoramide) results in the isolation of 1 : 1 carborane:hmpa adducts which provide the first definitive X-ray structures of the unsubstituted carboranes as part of three very different C–H⋯O hydrogen-bonded supramolecular structures.

Article information

Article type
Paper

Chem. Commun., 1996, 2285-2286

Definitive crystal structures of ortho-, meta- and para-carboranes: supramolecular structures directed solely by C–H⋯O hydrogen bonding to hmpa (hmpa = hexamethylphosphoramide)

M. G. Davidson, T. G. Hibbert, J. A. K. Howard, A. Mackinnon and K. Wade, Chem. Commun., 1996, 2285 DOI: 10.1039/CC9960002285

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